Syntheses with. alpha.-heterosubstituted phosphonate carbanions. 10. Autoxidation of the anion

H Zimmer, RE Koenigkramer, RL Cepulis…

文献索引：Zimmer, Hans; Koenigkramer, Rusty E.; Cepulis, R. L.; Nene, D. M. Journal of Organic Chemistry, 1980 , vol. 45, p. 2018 - 2020

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被引用次数: 12

摘要

Scheme I11 oxidation of ketones in basic solutionsJO that the reaction is somewhat similar to the one in Scheme 111. Though preparatively not as valuable as the autoxidation of triphenylmethyleneph~ sphoranes~-~ and of certain phosphine oxides6 the method described here might very well be the method of choice to transform aromatic aldehydes in a two-step synthesis into the corresponding acid anilides, especially 4-nitroanilides (Table ...