Tetrahedron

Reinvestigation of the synthetic and mechanistic aspects of Mn (III) acetate mediated oxidation of enones

AS Demir, Ö Reis, AC Igdir

文献索引：Demir, Ayhan S.; Reis, Oemer; Igdir, A. Cigdem Tetrahedron, 2004 , vol. 60, # 15 p. 3427 - 3432

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被引用次数: 34

摘要

Mn (OAc) 3 mediated α′-acetoxylation of α, β-unsaturated enones is reinvestigated from a synthetic and mechanistic point of view and an improved procedure based on the use of acetic acid as a co-solvent is presented. Excellent results were obtained for a variety of structurally diverse and synthetically important enones under the optimized conditions.