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Preparation of Arylethynylcarbinols

ET Clapperton, WS Macgregor

文献索引:Clapperton; MacGregor Journal of the American Chemical Society, 1949 , vol. 71, p. 3234

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被引用次数: 5

摘要

Discussion.-In view of the higher base strength of cyanide ion, it would seem surprising that carbon monoxide is capable of displacing it. The apparent similarity in the strength of bonding to nickel can be understood in terms of the double bonded situation in nickel carbonyl and the argument that the cyanide is chiefly single bonded.