Tetrahedron

Reductive addition to electron-deficient olefins with trivalent iodine compounds

H Togo, M Aoki, M Yokoyama

文献索引：Togo, Hideo; Aoki, Masahiko; Yokoyama, Masataka Tetrahedron, 1993 , vol. 49, # 36 p. 8241 - 8256

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被引用次数: 35

摘要

(Diacyloxyiodo) arene was treated with electron-deficient olefins in the presence of hydrogen donor such as 1, 4-cyclohexadiene to give the reductive addition products via alkyl radical through the radical decarboxylative pathway in good yields. Moreover, this system was able to generate either alkoxycarbonyl radicals or alkyl radicals with [bis (alkoxyoxalyloxy) iodo] benzene, which was prepared from alcohol, oxalyl chloride, and ( ...