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Reactions of 4a-peroxides and 4a-pseudobases of N10-and N5-phenethylflavins

…, TC Bruice, HL Carrell, JP Glusker

文献索引:Iwata, Masaki; Bruice, Thomas C.; Carrell, H. L.; Glusker, Jenny P, Journal of the American Chemical Society, 1980 , vol. 102, # 15 p. 5036 - 5044

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被引用次数: 25

摘要

Abstract: A number of NS, N'o-dialkylisoalloxazines have been synthesized in which either the fl or the NIo substituent is a meta-substituted phenethyl group. Some of these compounds have been subjected to experiments in order to determine whether an intramolecular transfer of oxygen can occur between the flavin and the phenyl group (a model for monooxygenase). When in the 1J-dihydro reduced state, fl-alkyl-substituted ...