Polymer chemistry. Part 1. Model compounds related to hexafluoropropenevinylidene fluoride elastomer

GC Aspey, RD Chambers, MJ Salisbury…

文献索引：Apsey, G. C.; Chambers, R. D.; Salisbury, M. J.; Moggi, G. Journal of Fluorine Chemistry, 1988 , vol. 40, p. 261 - 282

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被引用次数: 36

摘要

Abstract Model compounds related to the important elastomer derived from CH 2 2 CF 2/CFCF 3 are synthesised from telomers (CF 3) 2 CF (CH 2 CF 2 n I, by coupling and by fluorodeiodination reactions. These models, in reactions with bases, give information relating to mechanism of cross-linking of the polymer and indications of factors that limit its working life. Novel use of SbF 5 for dehydrofluorination in synthesis of fluorinated mono- ...