前往化源商城

举例 :可输入Filippa Pettersson 或者 Cancer Res. 75(6) , 1102-12, (2015) 或者10.1002/anie.201600521

Synthesis and absolute stereochemistry of roseophilin

PE Harrington, MA Tius

文献索引：Stetter, Hermann; Haese, Wilfried Chemische Berichte, 1984 , vol. 117, # 2 p. 682 - 693

全文：HTML全文

被引用次数: 120

摘要

... Volume: Page ... The transformation was accomplished very conveniently through the Stetter reaction of 18 with 6-heptenal 19 ... 22R,23R)-roseophilin in 15 steps and in 7.0% overall yield from 5-hexenal 13, taking into consideration the loss during crystallization of 2.

2-methylidene-2,3-dihydro-1H-inden-1-one结构式

2-methylidene-2...

正丁醛结构式

~75%

2-(2-oxopentyl)-2,3-dihydroinden-1-one结构式

2-(2-oxopentyl)...

查看详情

2-[(dimethylamino)methyl]-2,3-dihydroinden-1-one结构式

2-[(dimethylami...

~%

2-(2-oxopentyl)-2,3-dihydroinden-1-one结构式

2-(2-oxopentyl)...

查看详情

Spiro(bicyclo(2.2.1)hept-5-en-2,2'-indan)-1'-on结构式

Spiro(bicyclo(2...

~%

2-(2-oxopentyl)-2,3-dihydroinden-1-one结构式

2-(2-oxopentyl)...

查看详情

Spiro(bicyclo(2.2.1)hept-5-en-2,1'-cycloheptan)-2'-on结构式

Spiro(bicyclo(2...

~77%

2-methylidenecycloheptan-1-one结构式

2-methylidenecy...

查看详情

未登录结构式

~%

2-methylidenecycloheptan-1-one结构式

2-methylidenecy...

查看详情

苯甲醛结构式

2-亚甲基环戊酮结构式

2-亚甲基环戊酮

~44%

2-phenacylcyclopentan-1-one结构式

2-phenacylcyclo...

查看详情

3',4'-Dihydrospiro[bicyclo[2.2.1]hept-5-en-2,2'(1'H)-naphthalin]-1'-on结构式

3',4'-Dihydrosp...

~94%

2-METHYLENE-1-OXO-1,2,3,4-TETRAHYDRONAPHTHALENE结构式

2-METHYLENE-1-O...

查看详情

丙醛结构式

2-亚甲基环戊酮结构式

2-亚甲基环戊酮

~66%

2-(2-oxobutyl)cyclopentan-1-one结构式

2-(2-oxobutyl)c...

查看详情

3',4'-Dimethylspiro(bicyclo(2.2.1)hept-5-en-2,1'-(3)cyclopenten)-2'-on结构式

3',4'-Dimethyls...

~87%

2,3-Dimethyl-5-methylene-2-cyclopenten-1-one结构式

2,3-Dimethyl-5-...

查看详情

2-methylidene-2,3-dihydro-1H-inden-1-one结构式

2-methylidene-2...

苯甲醛结构式

~50%

2-phenacyl-2,3-dihydroinden-1-one结构式

2-phenacyl-2,3-...

查看详情

2-[(dimethylamino)methyl]-2,3-dihydroinden-1-one结构式

2-[(dimethylami...

~%

2-phenacyl-2,3-dihydroinden-1-one结构式

2-phenacyl-2,3-...

查看详情

Spiro(bicyclo(2.2.1)hept-5-en-2,2'-indan)-1'-on结构式

Spiro(bicyclo(2...

~%

2-phenacyl-2,3-dihydroinden-1-one结构式

2-phenacyl-2,3-...

查看详情

正丁醛结构式

2-亚甲基环戊酮结构式

2-亚甲基环戊酮

~63%

2-(2-oxopentyl)cyclopentan-1-one结构式

2-(2-oxopentyl)...

查看详情

2-噻吩甲醛结构式

2-亚甲基环戊酮结构式

2-亚甲基环戊酮

~59%

2-(2-oxo-2-thiophen-2-ylethyl)cyclopentan-1-one结构式

2-(2-oxo-2-thio...

查看详情

2-methylidenecycloheptan-1-one结构式

2-methylidenecy...

正丁醛结构式

~32%

2-(2-oxopentyl)cycloheptan-1-one结构式

2-(2-oxopentyl)...

查看详情

未登录结构式

~%

2-(2-oxopentyl)cycloheptan-1-one结构式

2-(2-oxopentyl)...

查看详情

Spiro(bicyclo(2.2.1)hept-5-en-2,1'-cycloheptan)-2'-on结构式

Spiro(bicyclo(2...

~%

2-(2-oxopentyl)cycloheptan-1-one结构式

2-(2-oxopentyl)...

查看详情

2-METHYLENE-1-OXO-1,2,3,4-TETRAHYDRONAPHTHALENE结构式

2-METHYLENE-1-O...

丙醛结构式

~63%

2-(2-oxobutyl)-3,4-dihydro-2H-naphthalen-1-one结构式

2-(2-oxobutyl)-...

查看详情

3',4'-Dihydrospiro[bicyclo[2.2.1]hept-5-en-2,2'(1'H)-naphthalin]-1'-on结构式

3',4'-Dihydrosp...

~%

2-(2-oxobutyl)-3,4-dihydro-2H-naphthalen-1-one结构式

2-(2-oxobutyl)-...

查看详情

2-METHYLENE-1-OXO-1,2,3,4-TETRAHYDRONAPHTHALENE结构式

2-METHYLENE-1-O...

正己醛结构式

~83%

2-(2-oxoheptyl)-3,4-dihydro-2H-naphthalen-1-one结构式

2-(2-oxoheptyl)...

查看详情

3',4'-Dihydrospiro[bicyclo[2.2.1]hept-5-en-2,2'(1'H)-naphthalin]-1'-on结构式

3',4'-Dihydrosp...

~%

2-(2-oxoheptyl)-3,4-dihydro-2H-naphthalen-1-one结构式

2-(2-oxoheptyl)...

查看详情

2-METHYLENE-1-OXO-1,2,3,4-TETRAHYDRONAPHTHALENE结构式

2-METHYLENE-1-O...

苯甲醛结构式

~67%

2-phenacyl-3,4-dihydro-2H-naphthalen-1-one结构式

2-phenacyl-3,4-...

查看详情

3',4'-Dihydrospiro[bicyclo[2.2.1]hept-5-en-2,2'(1'H)-naphthalin]-1'-on结构式

3',4'-Dihydrosp...

~%

2-phenacyl-3,4-dihydro-2H-naphthalen-1-one结构式

2-phenacyl-3,4-...

查看详情

2-methylidenecycloheptan-1-one结构式

2-methylidenecy...

正戊醛结构式

~51%

2-(2-oxohexyl)cycloheptan-1-one结构式

2-(2-oxohexyl)c...

查看详情

未登录结构式

~%

2-(2-oxohexyl)cycloheptan-1-one结构式

2-(2-oxohexyl)c...

查看详情

Spiro(bicyclo(2.2.1)hept-5-en-2,1'-cycloheptan)-2'-on结构式

Spiro(bicyclo(2...

~%

2-(2-oxohexyl)cycloheptan-1-one结构式

2-(2-oxohexyl)c...

查看详情

糠醛结构式

2-METHYLENE-1-OXO-1,2,3,4-TETRAHYDRONAPHTHALENE结构式

2-METHYLENE-1-O...

~62%

2-[2-(furan-2-yl)-2-oxoethyl]-3,4-dihydro-2H-naphthalen-1-one结构式

2-[2-(furan-2-y...

查看详情

3',4'-Dihydrospiro[bicyclo[2.2.1]hept-5-en-2,2'(1'H)-naphthalin]-1'-on结构式

3',4'-Dihydrosp...

~%

2-[2-(furan-2-yl)-2-oxoethyl]-3,4-dihydro-2H-naphthalen-1-one结构式

2-[2-(furan-2-y...

查看详情

2-methylidene-2,3-dihydro-1H-inden-1-one结构式

2-methylidene-2...

丙醛结构式

~75%

2-(2-oxobutyl)-2,3-dihydroinden-1-one结构式

2-(2-oxobutyl)-...

查看详情

2-[(dimethylamino)methyl]-2,3-dihydroinden-1-one结构式

2-[(dimethylami...

~%

2-(2-oxobutyl)-2,3-dihydroinden-1-one结构式

2-(2-oxobutyl)-...

查看详情

Spiro(bicyclo(2.2.1)hept-5-en-2,2'-indan)-1'-on结构式

Spiro(bicyclo(2...

~%

2-(2-oxobutyl)-2,3-dihydroinden-1-one结构式

2-(2-oxobutyl)-...

查看详情