The Journal of Organic Chemistry

Dioxiranes: synthesis and reactions of methyldioxiranes

RW Murray, R Jeyaraman

文献索引：Murray, Robert W.; Jeyaraman, Ramasubbu Journal of Organic Chemistry, 1985 , vol. 50, # 16 p. 2847 - 2853

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被引用次数: 731

摘要

The peroxymonosulfate-acetone system produces dimethyldioxirane under conditions permitting distillation of the dioxirane from the synthesis vessel. The same conditions were used to prepare other methyldioxiranes. Solutions of dimethyldioxirane prepared in this manner were used to study ita chemical and spectroscopic properties. The caroate-acetone system was also used to study the chemistry of in situ generated dimethyldioxirane.