Canadian journal of chemistry

The chlorination of acetone: a complete kinetic analysis

JP Guthrie, J Cossar

文献索引：Guthrie, Peter J.; Cossar, John Canadian Journal of Chemistry, 1986 , vol. 64, p. 1250 - 1266

被引用次数: 25

摘要

Rate constants are reported for all of the major steps followed in the chlorination of acetone, including the chlorination of mono-and 1, 1-dichloroacetone, the chlorination of hydroxyacetone, the chlorination and hydroxide-catalyzed rearrangement of 1, 1- dihydroxyacetone, and the haloform cleavage of trichloroacetone. p K a values are reported for hydroxyacetone and monochloroacetone. Rate constants for the hydrolyses of ...

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