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举例 :可输入Filippa Pettersson 或者 Cancer Res. 75(6) , 1102-12, (2015) 或者10.1002/anie.201600521

The Journal of Organic Chemistry

Hydrogen cyanide chemistry. 9. Cycloaddition reactions and nitrenium ion type reactivity of diiminosuccinonitrile

T Fukunaga, RW Begland

文献索引：Fukunaga, Tadamichi; Begland, Robert W. Journal of Organic Chemistry, 1984 , vol. 49, p. 813 - 821

全文：HTML全文

被引用次数: 9

摘要

Cycloaddition reactions of diiminosuccinonitrile (DISN) with nucleophilic olefins yield a variety of products including [4+ 21 cycloadducts and aziridines. All of the products derived from l, &dienes, styrene, para-substituted styrenes, cycloheptatriene, norbornene, and norbornadiene can be accounted for by rearrangements of a common intermediate, zwitterionic aziridinium ion. We introduce the concept of reverse polarization and propose ...

4-氟苯乙烯结构式

氰化氧醛亚胺酰基结构式

氰化氧醛亚胺酰基

~76%

2-amino-3-[2-(4-fluorophenyl)aziridin-1-yl]but-2-enedinitrile结构式

2-amino-3-[2-(4...

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5-(2-furyl)-1,4,5,6-tetrahydropyrazine-2,3-dicarbonitrile结构式

5-(2-furyl)-1,4...

~%

5-(furan-2-yl)pyrazine-2,3-dicarbonitrile结构式

5-(furan-2-yl)p...

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2-Ethenylfuran结构式

~%

5-(furan-2-yl)pyrazine-2,3-dicarbonitrile结构式

5-(furan-2-yl)p...

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5-(4-methoxy-phenyl)-1,4,5,6-tetrahydro-pyrazine-2,3-dicarbonitrile结构式

5-(4-methoxy-ph...

~44%

5-(4-methoxyphenyl)pyrazine-2,3-dicarbonitrile结构式

5-(4-methoxyphe...

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2-amino-3-[2-(4-methoxyphenyl)aziridin-1-yl]but-2-enedinitrile结构式

2-amino-3-[2-(4...

~%

5-(4-methoxyphenyl)pyrazine-2,3-dicarbonitrile结构式

5-(4-methoxyphe...

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4-甲氧基苯乙烯结构式

4-甲氧基苯乙烯

氰化氧醛亚胺酰基结构式

氰化氧醛亚胺酰基

~17%

未登录结构式

5-(4-methoxyphenyl)pyrazine-2,3-dicarbonitrile结构式

5-(4-methoxyphe...

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4-甲基苯乙烯结构式

4-甲基苯乙烯

氰化氧醛亚胺酰基结构式

氰化氧醛亚胺酰基

~1%

2-amino-3-[2-(4-methylphenyl)aziridin-1-yl]but-2-enedinitrile结构式

2-amino-3-[2-(4...

5-(4-methylphenyl)pyrazine-2,3-dicarbonitrile结构式

5-(4-methylphen...

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4-异丙烯基甲苯结构式

4-异丙烯基甲苯

氰化氧醛亚胺酰基结构式

氰化氧醛亚胺酰基

~0%

5-(4-methylphenyl)pyrazine-2,3-dicarbonitrile结构式

5-(4-methylphen...

5-Methyl-5-p-tolyl-1,4,5,6-tetrahydro-pyrazine-2,3-dicarbonitrile结构式

5-Methyl-5-p-to...

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4-甲基苯乙烯结构式

4-甲基苯乙烯

氰化氧醛亚胺酰基结构式

氰化氧醛亚胺酰基

~63%

2-amino-3-[2-(4-methylphenyl)aziridin-1-yl]but-2-enedinitrile结构式

2-amino-3-[2-(4...

5-(4-methylphenyl)pyrazine-2,3-dicarbonitrile结构式

5-(4-methylphen...

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N-(4-Methoxybenzyl)-diaminomaleonitril结构式

N-(4-Methoxyben...

~%

5-(4-methoxyphenyl)pyrazine-2,3-dicarbonitrile结构式

5-(4-methoxyphe...

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(5S,6S)-5-(4-methoxyphenyl)-6-methyl-1,4,5,6-tetrahydropyrazine-2,3-dicarbonitrile结构式

(5S,6S)-5-(4-me...

~%

5-(4-methoxyphenyl)-6-methylpyrazine-2,3-dicarbonitrile结构式

5-(4-methoxyphe...

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茴香烯结构式

~%

5-(4-methoxyphenyl)-6-methylpyrazine-2,3-dicarbonitrile结构式

5-(4-methoxyphe...

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重氮甲烷结构式

N-(4-Methoxybenzyl)-diaminomaleonitril结构式

N-(4-Methoxyben...

~24%

2-amino-3-[2-(4-methoxyphenyl)aziridin-1-yl]but-2-enedinitrile结构式

2-amino-3-[2-(4...

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氰化氧醛亚胺酰基结构式

氰化氧醛亚胺酰基

2,5-降冰片二烯结构式

2,5-降冰片二烯

~9%

2,3-二氰基吡嗪结构式

2,3-二氰基吡嗪

2-Butenedinitrile, 2-amino-3-(3-azatricyclo[3.2.1.02,4]oct-6-en-3-yl)结构式

2-Butenedinitri...

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氰化氧醛亚胺酰基结构式

氰化氧醛亚胺酰基

2,5-降冰片二烯结构式

2,5-降冰片二烯

~10%

2,3-二氰基吡嗪结构式

2,3-二氰基吡嗪

未登录结构式

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氰化氧醛亚胺酰基结构式

氰化氧醛亚胺酰基

1-(二乙氨基)丙炔结构式

1-(二乙氨基)丙炔

~62%

5-(diethylamino)-6-methylpyrazine-2,3-dicarbonitrile结构式

5-(diethylamino...

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氰化氧醛亚胺酰基结构式

氰化氧醛亚胺酰基

cyclohexa-1,3-diene结构式

cyclohexa-1,3-diene

~79%

1,4,4a,5,6,8a-hexahydroquinoxaline-2,3-dicarbonitrile结构式

1,4,4a,5,6,8a-h...

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氰化氧醛亚胺酰基结构式

氰化氧醛亚胺酰基

2-(diethylamino)-1-phenylacetylene结构式

2-(diethylamino...

~48%

5-(diethylamino)-6-phenylpyrazine-2,3-dicarbonitrile结构式

5-(diethylamino...

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phenylene-ethylene结构式

phenylene-ethylene

氰化氧醛亚胺酰基结构式

氰化氧醛亚胺酰基

~59%

2-amino-3-(2-phenylaziridin-1-yl)but-2-enedinitrile结构式

2-amino-3-(2-ph...

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对氯苯乙烯结构式

对氯苯乙烯

氰化氧醛亚胺酰基结构式

氰化氧醛亚胺酰基

~51%

2-amino-3-[2-(4-chlorophenyl)aziridin-1-yl]but-2-enedinitrile结构式

2-amino-3-[2-(4...

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