Small-Ring Compounds. XXXIV. Carbonium Ion Reactions of 1-Methylcyclobutyl,(1-Methylcyclopropyl)-carbinyl and (β-Methylallyl)-carbinyl Derivatives1

EF Cox, MC Caserio, MS Silver…

文献索引：Cox,E.F. et al. Journal of the American Chemical Society, 1961 , vol. 83, p. 2719 - 2724

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被引用次数: 43

摘要

Introduction The striking facility with which cyclopropylcarbinyl, cyclobutyl and allylcarbinyl derivatives become interconverted in carbonium ion reactions, combined with the high solvolytic reactivity of cyclopropylcarbinyl and cyclobutyl derivatives, has aroused considerable interest as to the precise nature (s) of the intermediates involved. On the basis of the experimental evidence so far available3-9 we have proposed6-8 that unsymmetrical ...