The Journal of Organic Chemistry

Hydroboration of vinyl ethers with diisopinocampheylborane

PE Peterson, M Stepanian

文献索引：Peterson, Paul E.; Stepanian, Marshall Journal of Organic Chemistry, 1988 , vol. 53, # 9 p. 1903 - 1907

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被引用次数: 14

摘要

The reactions of diisopinocampheylborane with cyclic vinyl ethers having an exocyclic oxygen and with acyclic vinyl ethers having groups of varying size attached to oxygen were explored. Evidence of some interaction of the bulkier vinyl ethers with diisopinocampheylborane was obtained, but high enantiomeric excesses were not found. However, the hydroboration-oxidation of benzyl or diphenylmethyl vinyl ethers, followed ...