Studies toward the Synthesis of Pinolidoxin, a Phytotoxic Nonenolide from the Fungus Ascochyta p inodes. Determination of the Configuration at the C-7, C-8, and C-9 …
The absolute stereochemistry at the C-7, C-8, and C-9 chiral centers of pinolidoxin (1) has been determined by chemical and spectral methods. First, the synthesis of four stereoisomeric fully benzoylated 2, 3-erythro-1, 2, 3, 4-heptanetetrols, corresponding to ...
