Studies toward the Synthesis of Pinolidoxin, a Phytotoxic Nonenolide from the Fungus Ascochyta p inodes. Determination of the Configuration at the C-7, C-8, and C-9 …

L de Napoli, A Messere, D Palomba…

Index: De Napoli, Lorenzo; Messere, Anna; Palomba, Daniela; Piccialli, Vincenzo; Evidente, Antonio; Piccialli, Gennaro Journal of Organic Chemistry, 2000 , vol. 65, # 11 p. 3432 - 3442

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Citation Number: 23

Abstract

The absolute stereochemistry at the C-7, C-8, and C-9 chiral centers of pinolidoxin (1) has been determined by chemical and spectral methods. First, the synthesis of four stereoisomeric fully benzoylated 2, 3-erythro-1, 2, 3, 4-heptanetetrols, corresponding to ...