Rapid and convenient approach to amines: Reduction of imines using metallic calcium in ethylalcohol

…, N Egashira, C Simion, M Tashiro

文献索引：Mitoma, Yoshiharu; Egashira, Naoyoshi; Simion, Cristian; Tashiro, Masashi Revue Roumaine de Chimie, 2006 , vol. 51, # 7-8 p. 839 - 842

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摘要

The reduction of imines is one of the most significant and useful methods for preparation of the corresponding amines. 1 Many reduction processes were therefore widely investigated, 2 which include catalytic reduction3 as well as the use of metal hydrides (LiAlH4, NaBH4 or others), 1b, 4 transition metals complexes (such as Ir, 5 Rh, 6 Mo, 7 Ni, 8 Sn, 9 Ti, 10 Ru, 11 Sm12), different boron compounds or complexes13 or metal reduction systems–metal (Na ...