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KINETIC STUDY OF THE REACTIONS OF2??AMINO??5??CHLOROBENZOPHENONE WITH HCl in MeOH–H2O

NS Nudelman, RG De Waisbaum

文献索引:Nudelman, N. Sbarbati; Waisbaum, R. G. de Journal of Physical Organic Chemistry, 1997 , vol. 10, # 2 p. 97 - 106

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被引用次数: 6

摘要

Abstract The reaction of 2-amino-5-chlorobenzophenone (1) with 0· 5–2 M HCl was studied in 1: 1 (v/v) MeOH–H 2 O at 60 and 80 C. Products that were isolated were characterized as 2-(N-methylamino-5-chlorobenzophenone)(2), 2-amino-3, 5-dichlorobenzophenone (3), 2-N- methylamino-3, 5-dichlorobenzophenone (4), 2-(N, N)-dimethylamino-5- chlorobenzophenone (5), 2, 4-dichloro-10-methyl-9, 10-acridinone (6) and 2, 4-dichloro-9, ...