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Oxidation of styrene derivatives by peroxydisulfate (2-) ion-copper (II) in acetic acid and acetonitrile. Reaction paths in oxidations via radical cations

…, GM El-Taliawi, K Amarnath

文献索引:Walling, Cheves; El-Taliawi, Gamil M.; Amarnath, Kalyani Journal of the American Chemical Society, 1984 , vol. 106, p. 7573 - 7578

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被引用次数: 47

摘要

Abstract:@-Aryl carbonyl compounds are major products in the oxidation of a variety of styrene derivatives by S202--Cu". Evidence is presented that they arise via oxidation to a radical cation, nucleophilic addition of water to give a P-hydroxyalkyl radical, Cu" ...

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