Triorganotin Fluoride Structures: A Ligand Close??Packing Model with Predominantly Ionic Sn− F Bonds

…, F Rosche, M Schürmann, U Zachwieja…

文献索引：Beckmann, Jens; Horn, Dagmar; Jurkschat, Klaus; Rosche, Fred; Schuermann, Markus; Zachwieja, Uwe; Dakternieks, Dainis; Duthie, Andrew; Lim, Allan E. K. European Journal of Inorganic Chemistry, 2003 , # 1 p. 164 - 174

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被引用次数: 9

摘要

Abstract The synthesis and complete characterization by multinuclear NMR, infrared, and Mössbauer spectroscopy, by single crystal X-ray analysis, as well as by electrospray mass spectrometry of the new soluble triorganotin fluoride Me 2 PhSnF (1) is reported. The crystal structure of 1 reveals a rod-like polymeric structure in the solid state. Solutions of 1 in apolar solvents, such as toluene, contain mixtures of interconvertible oligomers. Ab initio MO ...