… structures of (dimethyl)[(1R, 2S, 4R)-1, 7, 7-trimethylbicyclo [2.2. 1] hept-2-yl] tin chloride and methyl (phenyl) bis [(1R, 2S, 4R)-1, 7, 7-trimethylbicyclo [2.2. 1] hept-2-yl] …

M Helliwell, EJ Thomas, LA Townsend

文献索引：Helliwell, Madeleine; Thomas, Eric J.; Townsend, Linda A. Journal of the Chemical Society. Perkin Transactions 1, 2002 , # 10 p. 1286 - 1296

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被引用次数: 1

摘要

During the course of our own work, enantiomerically enriched bicyclo[2.2.1]hept-2-yl(diphenyl )tin hydrides were prepared using Diels–Alder reactions of (E)-3-triphenylacrylates to assemble the bicyclic nucleus. 11–13 Functional group transformations then led to the preparation of several bicyclo[2.2.1]heptyltin hydrides including the ethers 12–15. These tin hydrides did not prove to be useful for asymmetric synthesis, although these preliminary studies were not carried ...