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Synthèse de Dérivés Fonctionnels Des Acides Aminés

J Hannart, A Bruylants

文献索引:Hannart,J.; Bruylants,A. Bulletin des Societes Chimiques Belges, 1963 , vol. 72, p. 423 - 442

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被引用次数: 1

摘要

Abstract The authors describe a new synthetic procedure for the preparation of aminocyanoesters, by which they have obtained ethyl-α-amino-γ-cyanobutyrate (m. 105 C) and ethyl-α-amino-δ-cyanovalerate (m. 132 C). The value of the aminocyanoesters as intermediates in the synthesis of natural or synthetic aminoacids has been demonstrated. Indeed the first one gives on hydrolysis glutamic acid and on reduction dl-ornithine ...