Synthèse de Dérivés Fonctionnels Des Acides Aminés

J Hannart, A Bruylants

Index: Hannart,J.; Bruylants,A. Bulletin des Societes Chimiques Belges, 1963 , vol. 72, p. 423 - 442

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Abstract

Abstract The authors describe a new synthetic procedure for the preparation of aminocyanoesters, by which they have obtained ethyl-α-amino-γ-cyanobutyrate (m. 105 C) and ethyl-α-amino-δ-cyanovalerate (m. 132 C). The value of the aminocyanoesters as intermediates in the synthesis of natural or synthetic aminoacids has been demonstrated. Indeed the first one gives on hydrolysis glutamic acid and on reduction dl-ornithine ...