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The Journal of Organic Chemistry

Preparation, characterization, and reactions of lithium and sodium tetraalkylboron compounds

R Damico

文献索引:Damico,R. Journal of Organic Chemistry, 1964 , vol. 29, p. 1971 - 1976

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被引用次数: 63

摘要

Lithium and sodium tetraalkylboron compounds have been prepared by the reaction of alkyllithium and alkylsodium reagents with trialkylboranes. These tetraalkylboron compounds show extreme reactivity toward air and were therefore identified by the formation of stable tetramet, hylammoniuni and t, etrabut, ylphosphonium derivatives. Unusual infrared and nmr absorption peaks at 2750-2800 cm.-I and 10-10.5 ppm, respectively, were ...