Rearrangement of strained dipolar species. I. Episulfoxides. Demonstration of the existence of thiosulfoxylates

JE Baldwin, G Höfle, SC Choi

文献索引：Baldwin,J.E. et al. Journal of the American Chemical Society, 1971 , vol. 93, p. 2810 - 2812

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被引用次数: 35

摘要

5% AgNO: saturated TEG on Chromosorb P at 0" column tempera-ture.(13) A recent report (cf. DC Dittmer, GE Kuhlmann, and GC Levy, J. Org. Chem., 35, 3676 (1970)) describes the results of pyrolysis of dibenzoylstilbene episulfoxide. We believe the difference between these results and our own to lie in the presence of aryl substituents in the stilbene cases, which allow interconversion to the postulated 1, 2-oxathietane.