Kinetics and mechanism of alkaline hydrolysis of (E)-O-(N-4-nitrophenylcarbamoyl) benzaldoximes in 30% aqueous ethanol

J Hladká, J Mindl, M Večeřa

文献索引：Hladka,J. et al. Collection of Czechoslovak Chemical Communications, 1977 , vol. 42, p. 3316 - 3324

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被引用次数: 2

摘要

Alkaline hydrolysis of (E)-O-(N-4-nitrophenyJcarbamoyl) benzaldoximes (1) gives 4- nitrophenyl carbamate (which is further decomposed to 4-nitroaniline) and (E)-benzaldo~ imates (which are hydrolyzed to benzaldehydes). The hydrolysis of (E)-O-(N-methyl-N-4- nitrophenyJcarbamoyl)-benzaldoximes (II) gives directly N-methyl-4-nitroaniline and (E)- benzaldoximates. The hydrolysis velocities have been measured for a series of six ...