ARYL-VINYLSULFONE—REAGENTIEN ZUM SCHUTZ UND NACHWEIS VON THIOLFUNKTIONEN

L Horner, H Lindel

文献索引：Horner, L.; Lindel, H. Phosphorus and Sulfur and the Related Elements, 1983 , vol. 15, p. 1 - 8

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被引用次数: 17

摘要

Abstract Aryl vinyl sulfones selectively react with thiol groups to acid-stable compounds which easily are cleaved by mild bases to thiol compounds. Ester and amide groups are not attacked under these conditions. Therefore, these compounds are good protecting groups or labels in peptide chemistry. The following aryl vinyl sulfones were investigated: phenyl vinyl sulfone 1, p-carbethoxyphenyl vinyl sulfone 15 and the fluorescent 5- ...