The Journal of organic chemistry

2, 6, 7-Trithiabicyclo [2.2. 2] octanes as promising photolabile tags for combinatorial encoding

RA Valiulin, AG Kutateladze

文献索引：Valiulin, Roman A.; Kutateladze, Andrei G. Journal of Organic Chemistry, 2008 , vol. 73, # 1 p. 335 - 338

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被引用次数: 10

摘要

The adducts of trithiabicyclo [2.2. 2] octane (TTBO) and carbonyl compounds undergo efficient photoinduced fragmentation with quantum yields comparable to that of dithiane adducts. The effect of the third sulfur on the stability of the respective radical cations and radicals is examined computationally and experimentally in a laser flash photolysis study. A straightforward synthetic approach to a variety of 4-substituted trithiabicyclo [2.2. 2] ...