Chemistry–A European Journal

Transition??Metal??Free Synthesis of Conjugated Polymers from Bis??Grignard Reagents by Using TEMPO as Oxidant

MS Maji, T Pfeifer, A Studer

文献索引：Maji, Modhu Sudan; Pfeifer, Thorben; Studer, Armido Chemistry - A European Journal, 2010 , vol. 16, # 20 p. 5872 - 5875

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被引用次数: 43

摘要

Conjugated polymers have become important materials as the emissive medium in light- emitting diodes (LED).[1] In that regard poly (2, 7-fluorenes)(PF) are often used due to their valuable optical and electrical properties.[2] Different methods for the preparation of this important substance class have been developed. Initially, polyfluorene was prepared by oxidative coupling of fluorene.[3] However, regioselectivity problems occurred. ...