The Addition of Hydrogen Fluoride to Acetylenic Compounds

AL Henne, EP Plueddeman

文献索引：Henne; Plueddeman Journal of the American Chemical Society, 1943 , vol. 65, p. 588

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被引用次数: 16

摘要

The addition of hydrogen fluoride to acetylene homologs has been described recently by Grosse and Linn.'In general they operated on one-half or one-quarter gram mole, in closed vessels, at temperatures ranging between-40 and-70'and obtained yields from 46 to 76%. In the treatment of larger quantities (5-10 moles), we have found it desirable to resort to different procedures in order to avoid localized hot spots which cause resinification, as ...