Tetrahedron

Experimental and theoretical studies on the reactivities of partially and fully fluorinated primary alkyl radicals

MD Bartberger, WR Dolbier, J Lusztyk, KU Ingold

文献索引：Bartberger, Michael D.; Dolbier Jr., William R.; Lusztyk; Ingold Tetrahedron, 1997 , vol. 53, # 29 p. 9857 - 9880

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被引用次数: 40

摘要

Absolute rate constants for hydrogen abstraction from n-Bu3SnH by a number of partially- fluorinated and fully fluorinated n-alkyl radicals have been measured. The CH and CC bond dissociation energies for a number of pertinent hydrofluorocarbons have been calculated by DFT. The rate data are compared with those for addition of the same radicals to styrene, and the reactivities of these radicals are discussed in terms of their electronegativies, their ...