Tetrahedron letters

An easy access to α, β-unsaturated thioacylsilanes: a useful route to silylated 1, 2-dithiins

A Capperucci, A Degl'Innocenti, S Biondi, T Nocentini…

文献索引：Capperucci, Antonella; Degl'Innocenti, Alessandro; Biondi, Simona; Nocentini, Tiziano; Rinaudo, Giuseppe Tetrahedron Letters, 2003 , vol. 44, # 14 p. 2831 - 2835

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被引用次数: 12

摘要

Treatment of different silylated allenes with hexamethyldisilathiane (HMDST) in the presence of CoCl2· 6H2O affords an easy and high yielding access to α, β-unsaturated thioacylsilanes, which undergo a self-dimerization reaction to afford polyfunctionalized 1, 2- dithiins as the major products.