A MECHANISM ON GENERATION AND RECYCLE OF THE SELENENYLATING REAGENTS IN ELECTROCHEMICAL OXYSELENENYLATION— …

K Uneyama, M Ono, S Torii

文献索引：Uneyama, Kenji; Ono, Michio; Torii, Sigeru Phosphorus and Sulfur and the Related Elements, 1983 , vol. 16, p. 35 - 44

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被引用次数: 10

摘要

Abstract The transformation of olefins 1 into allylic ethers and alcohols 2 (R [dbnd] Me or H) was performed in 70–90% yields, using a catalytic amount of diphenyl diselenide, by an electrochemical oxyselenenylation-deselenenylation sequence. The electrooxidation of diphenyl diselenide in methanol or aqueous acetonitrile generates selenenylating reagents (PhSeOMe or PhSeOH), which subsequently react with 1 to produce the corresponding ...