Tetrahedron letters

The diethylisopropylsilyl group: A new protecting group for alcohols

K Toshima, S Mukaiyama, M Kinoshita, K Tatsuta

文献索引：Toshima; Mukaiyama; Kinoshita; Tatsuta Tetrahedron Letters, 1989 , vol. 30, # 46 p. 6413 - 6416

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被引用次数: 35

摘要

Abstract The diethylisopropylsilyl (DEIPS) group which is a new protective group for alcohols has been first characterized. DEIPS group can be distinguished from t-butyldimethylsilyl, triethylsilyl, tetrahydropyranyl groups and 2-deoxy glycoside with high selectivity in removing under mild acidic condition, although DEIPS group has high stability to many useful organic synthetic reaction conditions.