Tetrahedron letters

The diethylisopropylsilyl group: A new protecting group for alcohols

K Toshima, S Mukaiyama, M Kinoshita, K Tatsuta

Index: Toshima; Mukaiyama; Kinoshita; Tatsuta Tetrahedron Letters, 1989 , vol. 30, # 46 p. 6413 - 6416

Full Text: HTML

Citation Number: 35

Abstract

Abstract The diethylisopropylsilyl (DEIPS) group which is a new protective group for alcohols has been first characterized. DEIPS group can be distinguished from t-butyldimethylsilyl, triethylsilyl, tetrahydropyranyl groups and 2-deoxy glycoside with high selectivity in removing under mild acidic condition, although DEIPS group has high stability to many useful organic synthetic reaction conditions.

 Related Synthetic Route
N/A Structure

126889-46-1

N/A

~79%

5-(oxan-2-yloxy)pentan-1-ol Structure

76102-74-4

5-(oxan-2-yloxy...

N/A Structure

126909-56-6

N/A

~12%

2,5-Hexanediol Structure

2935-44-6

2,5-Hexanediol

5-((tert-butyldimethylsilyl)oxy)hexan-2-ol Structure

112150-43-3

5-((tert-butyld...

N/A Structure

126889-54-1

N/A

N/A Structure

126889-50-7

N/A

~5%

2,5-Hexanediol Structure

2935-44-6

2,5-Hexanediol

N/A Structure

126889-52-9

N/A

3,3,10,10-tetraethyl-2,5,8-trimethyl-4,9-dioxa-3,10-disiladodecane Structure

126889-51-8

3,3,10,10-tetra...

~15%

2,5-Hexanediol Structure

2935-44-6

2,5-Hexanediol

N/A Structure

126889-54-1

N/A

N/A Structure

126889-53-0

N/A


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