An asymmetric synthesis of 2, 4-dimethylvalerolactone and mevalonolactone using chiral binaphtyldiamine derivatives

Y Kawakami, J Hiratake, Y Yamamoto

文献索引：Kawakami, Yukio; Hiratake, Jun; Yamamoto, Yukio; Oda, Jun'ichi Journal of the Chemical Society, Chemical Communications, 1984 , # 12 p. 779 - 781

全文：HTML全文

被引用次数: 31

摘要

Syntheses of optically active lactones through discrimination chiral imides3 have also been reported. The selective ring between enantiotopic groups have been successfully achieved opening of prochiral cyclic acid anhydrides has been attemp- using dehydrogenases and hydrolases.1 Non-enzymic asym- ted4 but the selectivity was too low for efficient syntheses of metric syntheses involving selective use of a chiral 1,3- optically active lactones. We ...