Biocatalytic cleavage of alkenes with O2 and Trametes hirsuta G FCC 047

M Lara, FG Mutti, SM Glueck…

文献索引：Lara, Miguel; Mutti, Francesco G.; Glueck, Silvia M.; Kroutil, Wolfgang European Journal of Organic Chemistry, 2008 , # 21 p. 3668 - 3672

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被引用次数: 10

摘要

Abstract Alkenes possessing a C= C double bond adjacent to an aromatic ring were cleaved to yield the corresponding carbonyl compounds by use of molecular oxygen as the sole oxidant and a cell-free extract of the wood-degrading fungus Trametes hirsuta FCC 047 as catalyst. The oxygen pressure required was optimized. Special adapted equipment allowed 96 reactions to be performed in parallel under controlled oxygen pressure. A broad ...