Resolution and absolute configuration of K-region trans dihydrodiols from polycyclic aromatic hydrocarbons

…, PJ Van Bladeren, N Shirai, DM Jerina

文献索引：Balani, S. K.; Bladeren, P. J. van; Shirai, N.; Jerina, D. M. Journal of Organic Chemistry, 1986 , vol. 51, # 10 p. 1773 - 1778

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被引用次数: 29

摘要

K-region trans dihydrodiols of benzo [c] phenanthrene, chrysene, pyrene, and dibenz [c, h] acridine have been resolved as their diastereomeric diesters with (-)-(menthy1oxy) acetic acid, and their absolute configurations have been assigned by the application of circular dichroism and exciton chirality methods. For these as well as the K-region trans dihydrodiol derivatives from five other hydrocarbons, a consistent pattern of physical properties has ...