The evidence for generation of dimethylaminocyanocarbene in the thermolysis of dimethylaminomalononitrile. The dimethylamino (dicyano-and cyano) methyl …
L De Vries
文献索引：de Vries,L. Journal of the American Chemical Society, 1978 , vol. 100, p. 926 - 933
Abstract: Neat dimethylaminomalononitrile (1) decomposes at ambient temperature to give the very persistent dimethylaminodicyanomethyl radical (5). The g value and the hyperfine splitting constants, determined by computer simulation of the ESR spectrum, are consistent with this structure. The structure of 5 is confirmed by its thermal generation from the monodeuterio analogue of 1 and by its alternative generation through hydrogen atom ...
