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Water Superstructures within Organic Arrays; Hydrogen??Bonded Water Sheets, Chains and Clusters

NS Oxtoby, AJ Blake, NR Champness…

文献索引:Oxtoby, Neil S.; Blake, Alexander J.; Champness, Neil R.; Wilson, Claire Chemistry - A European Journal, 2005 , vol. 11, # 16 p. 4643 - 4654

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被引用次数: 83

摘要

Abstract A strategy for encouraging the formation of extended water arrays is presented, in which molecules that contain a 1, 4-dihydroquinoxaline-2, 3-dione core are used as supramolecular hosts for the accommodation of guest water molecules and arrays. These molecules were selected as they contain a hydrophilic oxalamide-based “terminus” that allows water molecules to hydrogen-bond to the host organic molecules as well as to ...