Transannular ozonides of 9-alkoxyanthracenes

J Rigaudy, G Chelu, NK Cuong

文献索引：Rigaudy, Jean; Chelu, Gerard; Cuong, Nguyen Kim Journal of Organic Chemistry, 1985 , vol. 50, # 23 p. 4474 - 4478

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被引用次数: 7

摘要

Ozonation of 9-alkoxyanthracenes in methanol at-78" C leads to transannular ozonides 7, most of which can be isolated in crystalline form. On warming in CH2C12, ozonides 7 undergo around-30 OC a decomposition with O2 release leading mainly to 10-alkoxy-9- anthrones 8. The radical character of this decomposition is established, in the case of 9- methoxy-10-methylanthracene ozonide (7e), by adding H donors such as 2, 4, 6-tri-tert- ...