Elucidation of the electron transfer reduction mechanism of anthracene endoperoxides

RL Donkers, MS Workentin

文献索引：Donkers, Robert L.; Workentin, Mark S. Journal of the American Chemical Society, 2004 , vol. 126, # 6 p. 1688 - 1698

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被引用次数: 57

摘要

The homogeneous and heterogeneous reductions of the endoperoxides 9, 10-diphenyl-9, 10-epidioxyanthracene (DPA-O 2) and 9, 10-dimethyl-9, 10-epidioxyanthracene (DMA-O 2) were investigated, and they were found to undergo a dissociative electron-transfer reduction of the OO bond to yield a distonic radical anion, with no evidence for CO bond dissociation. A number of thermochemical parameters for each were determined using Savéant's ...