Regiospecific synthesis of terminal, oxyfunctionalized methyl ketone enamines via catalytic aminomercuriation of prop-2-ynyl esters and ethers

J Barluenga, F Aznar, R Liz, C Postigo

文献索引：Barluenga, Jose; Aznar, Fernando; Liz, Ramon; Postigo, Carmen Journal of the Chemical Society, Chemical Communications, 1986 , # 19 p. 1465 - 1467

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被引用次数: 3

摘要

Catalytic aminomercuriation of 1-substituted prop-2-ynyl esters and ethers (5) provides a mild, simple, and regiospecific route to the terminal functionalized enamines (6) despite the fact that they are potentially isomerisable to their internal form; hydrolysis of (6) furnishes α- oxyketones (7).