Oxidation of an αβ-(epoxyalkyl) trimethylsilane with pyridine oxides in the presence of silylating agents. A facile enantioselective synthesis of glyceraldehyde …
P Raubo, J Wicha
文献索引:Raubo, Piotr; Wicha, Jerzy Tetrahedron Letters, 1994 , vol. 35, # 20 p. 3387 - 3390
Download full text in PDF Opens in a new window. Article suggestions will be shown in a dialog on return to ScienceDirect. ... Please enable JavaScript to use all the features on this page. ... Trimethylsilyl glycidol derivatives 1 were oxidized with pyridine N-oxides in the presence of silylating agents to give the corresponding glyceraldehyde derivatives 3. Reaction of (α,β-epoxyalkyl)silanes with N-oxides was studied. ... Aldehyde 4 was transformed to 1,1-dithiophenyl-2,3- ...