Carbene and silicon routes as methods for the generation and dipolar cycloaddition reactions of methyl nitrile ylide

A Padwa, JR Gasdaska, M Tomas…

文献索引：Padwa,A.; Gasdaska,J.R.; Tomas,M. Journal of the American Chemical Society, 1986 , vol. 108, p. 6739

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被引用次数: 47

摘要

Conclusion This study fails to support bicycloaromaticity as a significant factor in determining radical cation structures. In contrast, homoaromaticity is Seen to provide stabilization to the extent that the intramolecular [3+ 21 cycloaddition of y+ to homoaromatic a homoaromatic radical cation structure type. As with several Other recent examples from Our laboratory, we note that the potential energy surfaces of radical cation and the corresponding neutral ...