Organic letters

Rhodium Catalyzed Cyanation of Chelation Assisted C–H Bonds

M Chaitanya, D Yadagiri, P Anbarasan

文献索引：Chaitanya, Manthena; Yadagiri, Dongari; Anbarasan, Pazhamalai Organic Letters, 2013 , vol. 15, # 19 p. 4960 - 4963

全文：HTML全文

被引用次数: 53

摘要

A rhodium-catalyzed cyanation of chelation assisted C–H bonds is described employing N- cyano-N-phenyl-p-methylbenzenesulfonamide as an efficient cyanating reagent. The present method allowed the synthesis of various benzonitirle derivatives in good to excellent yield. A number of chelating groups are also effective in the present cyanation of C–H bonds. In addition, the developed methodology was applied in the formal synthesis of the ...