The Mechanism of Fluorination. IV. 1 The Effect of Temperature and of Fluorine Concentration upon the Olefin Dimerization Reaction. A New Fluorination Apparatus2

WT Miller, JO Stoffer, G Fuller…

文献索引：Miller,W.T. et al. Journal of the American Chemical Society, 1964 , vol. 86, p. 51 - 56

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被引用次数: 18

摘要

The interrelated effects of temperature and fluorine concentration on fluorine-olefin reactions have been investigated with some perhaloolefins. Reactions were carried out at low temperatures in a new apparatus which was equipped with a novel high speed nickel gauze stirrer, gas disperser. Reproducible results were obtained with weight recoveries of 95% or better. n'ith. CF3CF= CFCF3, increasing the effective fluorine concentration greatly ...