The behaviour of chlorofluoroethanes on β-aluminium (III) fluoride: a [36Cl] radiotracer study

H Bozorgzadeh, E Kemnitz, M Nickkho-Amiry…

文献索引：Bozorgzadeh, Hamid; Kemnitz, Erhard; Nickkho-Amiry, Mahmood; Skapin, Tomaz; Tate, Graeme D.; Winfield, John M. Journal of Fluorine Chemistry, 2001 , vol. 112, # 2 p. 225 - 232

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被引用次数: 11

摘要

A [36Cl] radiotracer study of the behaviour of 1, 1, 2-trichlorotrifluoroethane on β-aluminium (III) fluoride at elevated temperature indicates that the isomerisation of CCl2FCClF2 to CCl3CF3 occurs by an intramolecular process. Isomerisation is followed by dismutation of CCl3CF3 to give CCl2FCF3 and CCl3CClF2. In neither reaction, surface Al–Cl groups are formed. The compound CCl3CClF2 undergoes further reaction, readily, apparently also ...