Chemistry Letters

Facile cleavage of Ge-C bonds of N-(germylmethyl) benzylamine derivatives. Generation of germyl anions.

D Terunuma, H Kizaki, T Sato, K Masuo, H Nohira

文献索引：Terunuma, Daiyo; Kizaki, Hiroaki; Sato, Takashi; Masuo, Koujiro; Nohira, Hiroyuki Chemistry Letters, 1991 , # 1 p. 97 - 100

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被引用次数: 2

摘要

The reactions of N-(germylmethyl) benzylamine derivatives with butyllithium were carried out. Facile cleavages of Ge–C bonds of the N-benzylgermylmethylamine derivatives giving the corresponding germyl anions and N-pentylbenzylamine were observed. The reaction mechanism of the Ge–C bond cleavage was discussed.