The Germanium-Carbon Bond Cleavage Reaction of (Germylmethyl) amine Derivatives. Mechanism and Stereochemistry.

D Terunuma, K Masuo, H Kizaki, H Nohira

文献索引：Terunuma, Daiyo; Masuo, Koujiro; Kizaki, Hiroaki; Nohira, Hiroyuki Bulletin of the Chemical Society of Japan, 1994 , vol. 67, # 1 p. 160 - 164

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被引用次数: 9

摘要

A facile cleavage reaction of the germanium–carbon bond of (germylmethyl) amine derivatives to give a germyl anion and an azomethine derivative was developed. The effects of substituents such as phenyl, benzyl, and ethyl groups on the germanium and nitrogen atoms of the (germylmethyl) amine derivatives on the cleavage reaction, were investigated. The mechanism was also investigated based on the stereochemistry of the cleavage ...