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Tetrahedron

Synthesis and crystal structures of fluorescent receptors for 9-butyladenine

B Lamale, WP Henry, LM Daniels, C Zhang, SM Klein…

文献索引:Lamale, Bassam; Henry, William P.; Daniels, Lee M.; Zhang, Cungen; Klein, Suzane M.; Jiang, Yu Lin Tetrahedron, 2009 , vol. 65, # 1 p. 62 - 69

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被引用次数: 6

摘要

Two pyrene containing fluorescent receptors, 2-(1-pyrenyl) benzoic acid (FR-1) and 8-(1- pyrenyl)-1-naphthoic acid (FR-2), have been designed and synthesized to mimic a pyrene dinucleotide for molecular recognition of 9-butyladenine (9-BuA). The X-ray crystal structures of the receptors FR-1 and FR-2 along with the binding substrate 9-BuA have been determined. FR-1 has the carboxyl group in the same plane as the phenyl group whereas ...