Journal of the American Chemical Society

Transition Metal Complex Promoted Rearrangements. Tricyclo [4.1. 0.02, 7] heptane and 1-Methyltricyclo [4.1. 0.0. 2, 7] heptane

P Gassman, T Atkins

文献索引：Gassman,P.G.; Atkins,T.J. Journal of the American Chemical Society, 1972 , vol. 94, p. 7748 - 7756

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被引用次数: 53

摘要

Abstract: The transition metal complex promoted isomerization of tricyclo [4.1. OO* J] heptane (5) and l-methyltricyclc [4.1. 0.02 J] heptane (13) has been studied in detail. Derivatives of copper, iridium, mercury, palladium, platinum, rhodium, ruthenium, tin, and zinc were found to readily bring about the rearrangement of 5 to norcarene, 3- methylenecyclohexene, or 1, 3-~ ycloheptadiene. Similarly, certain transition metal ...